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INDEX
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Geon, 306 Glass, 169 170 Glass effect, 285 286 Glass transition temperature, 29 32. See also Crystalline-amorphous features Glide operation, 626 Global rate constant, 394 GPC, see Gel permeation chromatography Gradient copolymer, 327, 437 438, 480 Graft copolymer, 137, 324 325, 327, 752 758 See also Chain copolymerization; Copolymer; Graft polymerization; Polymer reaction Graft polymerization, 137, 466 anionic, 757 758 cationic, 758 from, 753 onto, 752 radical, 324 325, 327, 753 757 step reaction, 137 through, 753 vinyl macromers, 753 754 See also Copolymer; Graft copolymer; Polymer reaction Granular polymerization, 298 Grex, 302 Grilamid, 143 Group transfer polymerization, 420 422, 438, 442 GRS rubber, 351, 529. See also SBR rubber Grubbs initiator, 590 592 GTP, see Group transfer polymerization Guayule rubber, 634 Gutta percha rubber, 634 Halar, 310 Half-life, 211 212 Halogenation of polymer, 748 750 Hammett relationship, 505, 507 508 Hard block, 142, 437 HDPE, see high density polyethylene Head addition in initiation, 235, Head-to-head placement, 144, 203 204 Head-to-tail placement, 144, 203 204, 235 Heat of polymerization, see Thermodynamics of polymerization Heat-cured silicone, see Room temperature vulcanization silicone Heat-resistant polymer, see High temperature polymer Hemiisotactic, 626 Herclor, 569 Heteroarm polymer, 441 443 Heterogeneous particle nucleation, 354
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Heterogeneous polymerization, 287, 297 298. See also Emulsion polymerization Heterotactic triad, 636 Hevea rubber, 634 Hexa, 125 H-H placement, see Head-to-head placement High-density polyethylene, 301 302, 696 697 High impact polystyrene, 530 High-mileage initiator, 645 High-performance polymer, see High-temperature polymer High-temperature polymer: ceramic, 170 171, 174 conjugated polymer, 163 167 coordination, 172 cycloaddition, 183 184 Diels-Alder reaction, 155 156, 183 184 inorganic polymer, 168 171 liquid crystalline polymer, 157 159 organometallic polymer, 172 174, 330 polyamide, 100 101 polybenzimidazole, 159 161 polybenzothiazole, 161 162 polybenzoxazole, 161 162 polycarbonate, 96 97 polyether, 146 150 polyimide, 151 155 poly(p-phenylene), 166 poly(p-phenylene vinylene), 166 polyphosphazene, 597 599 polyquinoline, 162 163 polyquinoxaline, 163 polysiloxane, 132 134, 595 597 polysul de, 151 polysulfone, 149 150 poly(p-xylylene), 311 312 reactive teleechelic oligomer, 155 156 requirements, 144 146 semi-inorganic polymer, 168 174, 330 silicate 168 169 spiro, 184 HIPS, see High impact polystyrene Homogeneous particle nucleation,, 354 Homolytic dissociation, 209 210 Homopolymer, 136 Homopolymerization, 465 Homopropagation, 467 Homotopic, 668 Hosta on, 310 Hostalen, 302 Hostyren, 304 H-T placement, see Head-to-tail placement Hydridation, 387
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INDEX
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Hydride elimination, 417 Hydride transfer, 387, 659 661 Hydrin, 569 Hydrocarbon resin, 411 412 Hydrogen transfer polymerization, 450 451. See also Acrylamide polymerization Hydrolytic polymerization of lactam, 569, 572 573 Hydrophobic interaction, 735 736 Hydrosilation, 134 Hyperbranched polymer, 175 177, 180 Hytrel, 143 Ideal copolymerization, 471 473 Imine polymerization, 586 588 Immobilized enzyme, 770 Immortal polymerization, 553 Impact polystyrene, see High impact polystyrene Implicit penultimate model, 513 515 Inclusion complex, 299 Indene, 412 Induced decomposition of initiator, 228 Induction period, 256 Infrared spectroscopy, see Spectroscopic analysis Inherent viscosity, 63 65 Inhibition: ionic polymerization, 388 radical polymerization autoinhibition in allyl monomer, 263 264 kinetics, 256 259 mechanism, 259 263 oxygen, 261 retardation, 255 256 types of inhibitors, 259 263 Inhibition constant, 257 259 Inhibition period, 256 Inhibitor, 255 Initiation, see Chain initiation Initiator, 198, 209, 576. See also Chain initiation; Ring-opening polymerization; Stereoselective polymerization Initiator-coinitiator complex, 375 Initiator ef ciency: de nition, 228 experimental determination, 232 235 mechanism, 228 232 Initiator half-life, 211 212 Initiator radical, 205 Initiator site control, see Enantiomorphic site control Inorganic polymer, 168 171 Interaction, 277 Interchange reaction, 83, 144
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Interfacial polymerization, 90 92 Intermolecular cyclization, 524 527 Internal Lewis base, 658, Interpenetrating polymer network, 143, 527 528 Intramolecular cyclization, 114, 524 527 Intramolecular solvation, 428, 435 436 Inverse emulsion polymerization, 367 Inverse miniemulsion polymerization, 367 Inverse suspension polymerization, 298 Ion pair, 373, 424 425, 429 433. See also Anionic chain polymerization; Cationic chain polymerization Ion-exchange polymer, 750 Ionizing radiation, 224 226, 381 382, 755 756 Ionomer, 531 IPN, see Interpenetrating polymer network IR, see Spectroscopic analysis Isocyanate, 55 63, 131 132, 451 Isocyanide polymerization, 451 Isomerism, 144, 619 620 Isomerization polymerization, 382 384 Isoprene, 310 Isoregic, 203 Isoselective polymerization, 624, 641 Isotactic, 622 Isotactic dyad, 636 Isotactic index, 644 Isotactic placement, 637 Isotactic polymer, 622 624. See also Stereoisomerism in polymers; Stereoselective polymerization Isotactic polymerization, see Isoselective polymerization Isotactic triad, 636 Isotropic, 157 IUPAC nomenclature, 12 16 Jeffox, 568 Kapton, 152 Kcal, see Kilocalorie Kelen-Tudos plot, 480 481 Kel-F, 310 Ketene, 449 450 Kevlar, 100 Kilocalorie, 88 Kilojoule, 88 KJ, see Kilojoule Kinetic chain length, 236 Kinetic penultimate effect, see Chain copolymerization; Copolymerization equation Kinetics: anionic chain polymerization, 422 436
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