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vinyl ether, 703 See also Coordination initiator; Stereoisomerism in polymers Stereospeci c polymerization, see Stereoselective polymerization, Steric effect: chain polymerization, 277 279 copolymerization, 496 497, 508, 511 hyperbranched polymer, 176 177 polymer reaction, 732 733 ring-opening polymerization, 545 546, 567, 577 Sterically-hindered pyridine, 376 Stoichiometric imbalance, 75 79 Stoichiometric ratio, 75 79 Stopped- ow method, 393 396 Stopper, 185 Strain, 34 Strength, 34 Stress-strain properties, see Mechanical properties Structural isomerism, 144, 619 620 Structural repeating unit, 12 Structural unit, 50 Styrene-acrylonitrile copolymer, 529 530, 738 Styrene-1,3-butadiene rubber, 351 353, 529 530, 738 Styrene-maleic anhydride copolymer, 143, 530 Styrofoam, 304 Styron, 304 Substituted ethylene, 4 6 Subunit, 12 Sulfur, 600, 739 742 Sulfur heterocyclic polymerization, 588 589 Sulfur nitride polymerization, 600 Sulfur polymerization, 600 Sulfur vulcanization, 739 742 Super acid, 769 Super glue, 414 Superactive initiator, 645 Supercritical carbon dioxide, 183 Supercritical uid, 183, 309 Support, 760 765 Supported initiator, 645, 664 665. See also Stereoselective polymerization Surfactant, 298, 352 353, 363 364 Surlyn, 531 Suspension polymerization, 297 298 Suspension stabilizer, 298 Switchboard model, 25 27 Syn addition, 654 655 Syncatalyst, 375 Syndioregic, 203 Syndioselective polymerization, 624, 641, 652 654
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Syndiotactic, 622 Syndiotactic dyad, 624 Syndiotactic placement, 637 Syndiotactic polymer, 622 624. See also Stereoisomerism in polymers; Stereoselective polymerization Syndiotactic triad, 636 Tacticity, 622 624, 635 637 Taft equation, 505 Tail, 144 Tail addition in initiation, 235 Tail-to-tail structure, see Head-to-head structure Tandem polymerization, 681 Tapered copolymer, 437 438. See also Gradient copolymer TA process, 93 Tecno on, 533 Tedlar, 310 Te on, 310 Tefzel, 310 Telechelic polymer, 140, 155 156, 321, 439 440, 759 Telomer, 238 239 Template polymerization, 287 289, 299 TEMPO, 325 328 Tensile strength, 34 Terathane, 568 Terluran, 530 Terminal model: copolymerization, 466 469, 505 506, 513 515 stereochemistry, 709 710 Termination, see Chain termination Terpolymerization, 464, 485 487 Terylene, 94 Tetrad, 636 Texin, 142 Thermal analysis, 27 Thermal initiation, 220 221, 226 227, 273 Thermal transition, 29 32 Thermally stable polymer, see High-temperature polymer Thermodynamics of polymerization: carbonyl monomer, 444 445 chain copolymerization, 515 518 radical chain reaction, 275 281, 296 ring-opening reaction, 545 546, 566 567 step polymerization, 65 69, 73 74, 81 Thermoplastic, 105 Thermoplastic elastomer, 142 143 Thermoplastic polyurethane, 142 143 Thermoset polymer, 105, 117 118
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Thermotropic liquid crystal, 157 159 Thietane polymerization, 588 589 Thiirane polymerization, 588 589 Thiokol, 135 Threo, 625 626, 632 Threodiisotactic polymer, 625 626, 632 Threodisyndiotactic polymer, 625 626, 632 Threshold pressure, 296 Tie molecule, 26 27 Tight ion pair, 373 374. See also Ion pair Topochemical polymerization, 184. See also Solid-state polymerization; Transport polymerization Torlon, 153 Torsional strain, 71 TPE, see Thermoplastic elastomer TPU, see Thermoplastic polyurethane Trade name, 16 Traditional Ziegler-Natta initiators, 640 665 Trans addition, 654 655 s-Trans conformation, 690 691 Transannular strain, 72 Transformation reaction, 324, 443 Transition probabilities, 469 470 Translational diffusion, 283 286 Transoid, 690 691 Trans-polymer, 629 634. See also Stereoisomerism in polymers; Stereoselective polymerization Transport polymerization, 311 313 Triad, 636 Triad tacticity, 636 637 Trifunctional monomer, 56 63 Trioxane polymerization, 561 562 Triphase catalyst, 770 Triple-ion, 435 436 Trommsdorff effect, 214, 282 289, 364 Twaron, 100 Two-ended living anion, 423 Two-prepolymer technique, 139 140 Two-strand polymer, see Ladder polymer Tybrene, 530 Ultem, 153 Ultimate elongation, 34 Ultimate strength, 34 Ultimate unit, 464 Ultrathene, 530 Ultraviolet-visible spectroscopy, see Spectroscopic analysis Unequal functional group reactivity: effect on crosslinking, 112 115 effect on rate and molecular weight, 54 63
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effect on molecular weight distribution, 86 87 Unpaired ion, 373 374 Unsaturated polyester, 118 120, 531 532 Urea-formaldehyde polymer, 126 128 UV, see Spectroscopic analysis Vapor pressure osmometry, 21 Vecta, 159 Verel, 308 Vespel, 152 Vestenamer, 591 Vinyl polymer, 304 306 Vinyl monomer, 4 6 Viscose rayon, 746 Viscosity, 22, 64 Viscosity-average molecular weight, 22. See also Molecular weight; Molecular weight distribution Viscosity effect, 488 489 Viton, 533 Vitri cation effect, 285 286 Volume of activation, 293 295 Vulcanizate, 742 Vulcanization of elastomers, 133, 738 742. See also Crosslinking Vygen, 306 Water-in-oil emulsion, 367 Weight-average functionality, 110 Weight-average molecular weight, 21 24. See also Molecular weight; Molecular weight distribution Weight-fraction, 21, 80 82 Wood, 745 Wool, 2 Wurtz coupling, 173 174 Xanthate, 330, 746 Xanthation, 745 746 Xerogel, 171 Xerography, 313 X-ray diffraction, 27 Xydar, 159 p-Xylylene, 311 313 Zero-order Markov model, 708 709 Ziegler or Ziegler-Natta initiator, see Coordination initiator; Stereoisomerism in polymers; Stereoselective polymerization Zip polymerization, 289 Zirconocene, 670 671 Zwitterion polymerization, 587 589, 605 606
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